I was led suspect that the enol form the rapidly curative one and that the needle form beneficial reason its gradual transformation into the enol in the tissues. The prism form has been tested some birds under varying conditions.
Doses from. milligrams have been tried injection and best sites to buy essays mouth. Injections in water have been made immediately after solution, after standing several days, after boiling, and after heating under steam pressure.
Injections in mineral oil and in fatty acid have also been tried.
In no case was there the slightest evidence any benefit. When large doses were administered, the action seemed distinctly adverse in several cases, as the birds died sooner than was expected.
Doses milligrams injected into healthy birds, however, produced no gross toxic symptoms.
This absolute lack curative properties very striking and suggestive. It apparent from the experimental evidence that the tautomeric forms exist in equilibrium and that there fairly rapid transformation in any direction.
One would therefore suppose that the prism form would, when injected into the body, rapidly convert itself into the curative form as the latter was removed from solution absorption in the tissues or fluids requiring That such not the case suggests very strongly that the pathological conditions polyneuritis are not due a deficiency a substance per but a lack a certain type potential energy which only that substance can supply. help me write a thesis sentence In other words, one led surmise that the potentiality tautomeric change that produces the desired result. In this connection interesting note university assignment writing service that many english proofreading online purine and pyrimidine derivatives, some which Funk has reported partially curative for polyneuritis, are also theoretically capable a similar tautomeriam. That these substances are a greater or less degree enol-keto tautomers very strongly indicated well-known reactions uric add, for example. The existence a third tautomer not excluded theoretical considerations, but lacks the support any experimental evidence. It appeared not unlikely that other hydroxy pyridines might prove more easily controlled. Accordingly and hydroxy pyridine and a a dimethyl hydroxy pyridine or lutidone have been prepared and are being tested. They show curative properties only under certain conditions.
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